夜雨聆风PDF#00-044-0141(RDB):质标=星印(S);d=衍射仪;I=衍射仪
Manganese Oxide
Mn O2 Black
射线=CuKa1 波长=1.54056 滤波法=Graph
校准=内部(Si) 2θ=12.784-120.917 I/Ic(K值)=
文献: Liles, D., Rossouw, M., Thackeray, M., Div. Mater. Sci. & Tech., CSIR, Pretoria, South Africa.
Private Communication(1992)
四方晶系-(未知),I4/m(87) Z=8
晶胞: 9.7847x9.7847x2.863 <90.0x90.0x90.0> P.S=tI24.00(á)
密度(计算)=4.213 密度(测量)= 分子量=86.94 体积=274.10 F(30)=46.1(0.0138,47/0)
文献: 出处同上
强峰线: 2.40/X 3.09/8 1.53/6 4.90/5 1.83/5 6.92/4 1.35/4 1.63/3
Analysis: Chemical analysis showed a residual Li+ content of only 0.029 wt.% and a residual H content of 0.03 wt.% (equivalent to a residual ''H2 O'' content of 0.29 wt.%).
Color: Black.
General Comments: Validated by Rietveld structure refinements using both X-ray and neutron diffraction data.
Sample Preparation: Prepared by acid treatment of ''Li2 Mn O3'' (prepared from electrolytic ''Mn O2'' and ''Li O H · H2 O'' at 800 C) with 1-5M ''H2 S O4'' at ~90 C and dried overnight at 300 C.
2θ d(埃) I(f) ( h k l) θ 1/(2d) 2π/d n^2
12.784 6.9190 37.0 ( 1 1 0) 6.392 0.0723 0.9081
18.108 4.8950 53.0 ( 2 0 0) 9.054 0.1021 1.2836
25.712 3.4620 5.0 ( 2 2 0) 12.856 0.1444 1.8149
28.842 3.0930 82.0 ( 3 1 0) 14.421 0.1617 2.0314
36.696 2.4470 24.0 ( 4 0 0) 18.348 0.2043 2.5677
37.523 2.3950 100.0 ( 2 1 1) 18.761 0.2088 2.6235
39.011 2.3070 9.0 ( 3 3 0) 19.505 0.2167 2.7235
41.226 2.1880 5.0 ( 4 2 0) 20.613 0.2285 2.8717
41.968 2.1510 28.0 ( 3 0 1) 20.984 0.2325 2.9211
46.038 1.9699 2.0 ( 3 2 1) 23.019 0.2538 3.1896
47.374 1.9174 8.0 ( 5 1 0) 23.687 0.2608 3.2769
49.865 1.8273 50.0 ( 4 1 1) 24.932 0.2736 3.4385
52.857 1.7307 <1 ( 4 4 0) 26.428 0.2889 3.6304
56.373 1.6308 29.0 ( 6 0 0) 28.186 0.3066 3.8528
56.928 1.6162 10.0 ( 4 3 1) 28.464 0.3094 3.8876
60.276 1.5342 58.0 ( 5 2 1) 30.138 0.3259 4.0954
65.109 1.4315 15.0 ( 0 0 2) 32.555 0.3493 4.3892
66.693 1.4013 1.0 ( 1 1 2) 33.346 0.3568 4.4838
67.649 1.3838 1.0 ( 7 1 0) 33.825 0.3613 4.5405
68.186 1.3742 5.0 ( 2 0 2) 34.093 0.3638 4.5723
69.713 1.3478 35.0 ( 5 4 1) 34.856 0.3710 4.6618
71.191 1.3234 <1 ( 2 2 2) 35.595 0.3778 4.7478
72.713 1.2994 8.0 ( 3 1 2) 36.357 0.3848 4.8355
73.701 1.2844 3.0 ( 7 3 0) 36.851 0.3893 4.8919
77.162 1.2352 4.0 ( 4 0 2) 38.581 0.4048 5.0868
78.590 1.2163 10.0 ( 3 3 2) 39.295 0.4111 5.1658
83.820 1.1532 2.0 ( 6 6 0) 41.910 0.4336 5.4485
84.350 1.1473 3.0 ( 5 1 2) 42.175 0.4358 5.4765
87.150 1.1175 2.0 ( 7 4 1) 43.575 0.4474 5.6225
91.465 1.0757 9.0 ( 6 0 2) 45.732 0.4648 5.8410
101.473 0.9949 2.0 ( 7 1 2) 50.737 0.5026 6.3154
102.907 0.9849 1.0 ( 6 4 2) 51.454 0.5077 6.3795
104.365 0.9751 2.0 ( 8 5 1) 52.182 0.5128 6.4436
111.409 0.9324 6.0 ( 2 1 3) 55.704 0.5363 6.7387
118.139 0.8980 2.0 ( 6 6 2) 59.069 0.5568 6.9969
120.917 0.8854 5.0 ( 4 1 3) 60.458 0.5647 7.0964
请在微信客户端打开
附图：
PDF#01-071-0636(RDB):质标=星印(S);d=计算值;I=计算值
Bixbyite, syn(Manganese Oxide)
Mn2 O3
射线=CuKa1 波长=1.5406 滤波法=
校准= 2θ=18.836-147.957 I/Ic(K值)=5.08
文献: Geller, S.
Acta Crystallogr., Sec. B: Struct. Crystallogr. Cryst. Chem., v27 p821(1971)
立方晶系-单晶衍射,Ia-3(206) Z=16
晶胞: 9.4146x9.4146x9.4146 <90.0x90.0x90.0> P.S=cI80.00
密度(计算)=5.027 密度(测量)= 分子量=157.87 体积=834.46 F(30)=999.9(0.0000,30/0)
文献: 出处同上
强峰线: 2.72/X 1.66/3 3.84/2 2.35/2 1.42/2 1.85/1 2.01/1 1.45/1
ANX: A2X3.
Analysis: Mn2 O3.
Formula from original source: Mn2 O3.
ICSD Collection Code: 9091.
Calculated Pattern Original Remarks: Calculated from ion size (2nd reference): a=9.450, x(Mn2)=.2816, xyz(O1)=.1310, .1352, -.1015, D=4.969.
Stable above 302 K (3rd ref., Tomaszewski), below Pbca.
Wyckoff Sequence: e d a(IA3-).
Unit Cell Data Source: Single Crystal.
2θ d(埃) I(f) ( h k l) θ 1/(2d) 2π/d n^2
18.836 4.7073 1.2 ( 2 0 0) 9.418 0.1062 1.3348 4
23.123 3.8435 17.7 ( 2 1 1) 11.561 0.1301 1.6348 6
26.761 3.3286 0.1 ( 2 2 0) 13.381 0.1502 1.8877 8
32.930 2.7178 100.0 ( 2 2 2) 16.465 0.1840 2.3119 12
35.653 2.5162 1.9 ( 3 2 1) 17.827 0.1987 2.4971 14
38.207 2.3537 17.4 ( 4 0 0) 19.104 0.2124 2.6696 16
40.624 2.2190 1.2 ( 4 1 1) 20.312 0.2253 2.8315 18
42.927 2.1052 0.8 ( 0 2 4) 21.463 0.2375 2.9846 20
45.134 2.0072 8.8 ( 3 3 2) 22.567 0.2491 3.1303 22
47.260 1.9218 1.3 ( 4 2 2) 23.630 0.2602 3.2695 24
49.316 1.8464 11.8 ( 4 3 1) 24.658 0.2708 3.4030 26
53.249 1.7189 2.7 ( 5 2 1) 26.625 0.2909 3.6554 30
55.141 1.6643 32.6 ( 4 4 0) 27.571 0.3004 3.7753 32
56.990 1.6146 1.6 ( 4 3 3) 28.495 0.3097 3.8915 34
58.802 1.5691 0.6 ( 6 0 0) 29.401 0.3187 4.0043 36
60.579 1.5273 3.8 ( 6 1 1) 30.289 0.3274 4.1141 38
62.325 1.4886 1.2 ( 6 2 0) 31.163 0.3359 4.2209 40
64.045 1.4527 5.7 ( 5 4 1) 32.022 0.3442 4.3252 42
65.739 1.4193 17.2 ( 6 2 2) 32.870 0.3523 4.4270 44
67.411 1.3881 4.4 ( 6 3 1) 33.705 0.3602 4.5264 46
69.063 1.3589 2.8 ( 4 4 4) 34.532 0.3680 4.6238 48
70.697 1.3314 0.7 ( 3 4 5) 35.348 0.3755 4.7191 50
72.315 1.3056 1.3 ( 6 4 0) 36.157 0.3830 4.8126 52
73.919 1.2812 2.1 ( 1 2 7) 36.959 0.3903 4.9043 54
75.509 1.2581 1.0 ( 2 4 6) 37.754 0.3974 4.9943 56
80.218 1.1957 1.1 ( 6 5 1) 40.109 0.4182 5.2550 62
81.771 1.1768 2.1 ( 8 0 0) 40.886 0.4249 5.3391 64
83.319 1.1589 2.4 ( 8 1 1) 41.659 0.4315 5.4219 66
84.861 1.1417 1.6 ( 0 2 8) 42.431 0.4379 5.5034 68
86.400 1.1253 1.8 ( 3 5 6) 43.200 0.4443 5.5838 70
87.937 1.1095 0.9 ( 8 2 2) 43.968 0.4506 5.6630 72
89.472 1.0944 1.3 ( 8 3 1) 44.736 0.4569 5.7411 74
91.005 1.0799 3.4 ( 6 6 2) 45.503 0.4630 5.8181 76
92.541 1.0660 0.2 ( 2 5 7) 46.270 0.4690 5.8942 78
94.078 1.0526 2.5 ( 0 4 8) 47.039 0.4750 5.9693 80
95.617 1.0397 0.5 ( 8 3 3) 47.808 0.4809 6.0434 82
97.161 1.0272 0.5 ( 8 4 2) 48.580 0.4868 6.1167 84
98.710 1.0152 1.3 ( 6 5 5) 49.355 0.4925 6.1891 86
100.266 1.0036 0.3 ( 6 6 4) 50.133 0.4982 6.2606 88
101.829 0.9924 0.9 ( 7 5 4) 50.914 0.5038 6.3314 90
104.984 0.9710 1.5 ( 3 6 7) 52.492 0.5149 6.4706 94
106.578 0.9609 1.8 ( 8 4 4) 53.289 0.5204 6.5390 96
108.186 0.9510 1.4 ( 3 5 8) 54.093 0.5258 6.6068 98
109.808 0.9415 0.5 ( 0 6 8) 54.904 0.5311 6.6739 100
111.448 0.9322 0.4 ( 7 7 2) 55.724 0.5364 6.7403 102
113.106 0.9232 2.3 ( 8 6 2) 56.553 0.5416 6.8060 104
114.785 0.9144 0.6 ( 9 4 3) 57.392 0.5468 6.8712 106
116.487 0.9059 1.9 (10,2,2) 58.243 0.5519 6.9357 108
118.214 0.8976 1.1 ( 5 6 7) 59.107 0.5570 6.9996 110
121.757 0.8818 1.5 ( 8 5 5) 60.879 0.5670 7.1257 114
123.580 0.8741 2.4 ( 4 6 8) 61.790 0.5720 7.1880 116
125.442 0.8667 1.3 ( 9 6 1) 62.721 0.5769 7.2497 118
127.348 0.8594 1.7 (2,4,10) 63.674 0.5818 7.3109 120
129.304 0.8524 1.3 ( 8 7 3) 64.652 0.5866 7.3715 122
133.392 0.8387 1.3 (1,2,11) 66.696 0.5961 7.4914 126
135.542 0.8321 0.3 ( 8 8 0) 67.771 0.6009 7.5506 128
140.113 0.8194 0.7 (10,4,4) 70.057 0.6102 7.6677 132
142.570 0.8133 0.7 (11,3,2) 71.285 0.6148 7.7256 134
145.172 0.8073 0.6 (10,6,0) 72.586 0.6194 7.7830 136
147.957 0.8014 0.8 ( 8 7 5) 73.978 0.6239 7.8400 138
附图：
PDF#01-075-0921(RDB):质标=定胞(I);d=计算值;I=计算值
Aluminum Oxide
( Al2 O3 )1.333
射线=CuKa1 波长=1.5406 滤波法=
校准= 2θ=39.482-145.631 I/Ic(K值)=1.08
文献: Verwey, E.J.W.
Z. Kristallogr., Kristallgeom., Kristallphys., Kristallchem., v91 p317(1935)
立方晶系-单晶衍射,Fm-3m(225) Z=1
晶胞: 3.95x3.95x3.95 <90.0x90.0x90.0> P.S=cF6.66(?)
密度(计算)=3.662 密度(测量)= 分子量=135.91 体积=61.63 F(9)=999.9(0.0002,9/0)
文献: 出处同上
强峰线: 1.98/X 1.40/9 0.81/2 0.88/1 1.14/1 0.99/1
ANX: A3X4.
Analysis: Al2.666 O3.999.
Formula from original source: (Al2 O3)1.333.
ICSD Collection Code: 30267.
Minor Warning: No e.s.d reported/abstracted on the cell dimension.
No R factors reported/abstracted.
Wyckoff Sequence: c b a(FM3-M).
Unit Cell Data Source: Single Crystal.
2θ d(埃) I(f) ( h k l) θ 1/(2d) 2π/d n^2
39.482 2.2805 4.9 ( 1 1 1) 19.741 0.2192 2.7551 3
45.912 1.9750 100.0 ( 2 0 0) 22.956 0.2532 3.1814 4
66.950 1.3965 94.2 ( 2 2 0) 33.475 0.3580 4.4991 8
80.598 1.1910 0.1 ( 3 1 1) 40.299 0.4198 5.2757 11
84.992 1.1403 9.4 ( 2 2 2) 42.496 0.4385 5.5103 12
102.530 0.9875 9.3 ( 4 0 0) 51.265 0.5063 6.3627 16
116.431 0.9062 0.1 ( 3 3 1) 58.215 0.5518 6.9336 19
121.411 0.8832 10.2 ( 4 2 0) 60.706 0.5661 7.1137 20
145.631 0.8063 21.3 ( 4 2 2) 72.815 0.6201 7.7927 24
附图：
感谢你读到这里
七七想与你分享每一个前进的脚印🌼
